生物接触氧化法处理制革综合废水中的常见问题及对策

探讨了生物接触氧化法处理制革综合废水时常见的出水水质波动大 ,硫化物、三价铬、悬浮物浓度高 ,易产生大量泡沫和曝气效果不理想等问题 ,提出了相应的解决措施。经制革厂运用实践证明 :改进后的生物接触氧化法处理制革综合废水是较为理想的方法     

Continuous precipitation of calcium sulfate dihydrate from waste sulfuric acid and lime

Precipitation of calcium sulfate dihydrate, gypsum, from (i) a pure sulfuric acid/lime suspension and (ii) a waste sulfuric acid/lime suspension in a continuous pilot plant in the temperature range from 40 °C to 80 °C was studied. It was observed that in the case of waste sulfuric acid with a high content of Mg²⁺ and Fe²⁺ ions, several hours after the beginning of the precipitation, partial dissolution of the product and modification of the crystals from needle‐ and plate‐like to agglomerated structures occurred. It is suggested that the secondary changes occur due to the increased concentration of Mg²⁺ and Fe²⁺ ions in the reactor. Below 60 °C, and above 70 °C plate‐like and needle‐like single crystals respectively were formed. The mean size (d₅₀) of the crystals was found to increase with increasing temperature and decrease with the initial concentration of lime. Gypsum produced between 70 °C and 80 °C is suitable for further processing for construction plaster. In a precipitation process with pure sulfuric acid only single perfect needle‐like crystals occurred. Copyright © 2005 Society of Chemical Industry     

Organic matter and nitrogen removal by an on site sewage treatment and disposal system

The performance of an on site sewage treatment and disposal system consisting of a septic tank, a gravel filter, a sand filter and soil absorption trenches operated alternatively, was studied in relation to organic matter and nitrogen removal efficiency. The system was simulated with the aid of a laboratory scale model. BOD₅ and SS removal efficiencies averaged 92.9 and 93.4% respectively. Substantial removal of nitrogen (up to 70%) was achieved due to nitrification followed by denitrification. Removal efficiencies were found to depend on the compaction characteristics of the filter media and the soil, the hydraulic loading applied and the flow conditions (saturated/unsaturated). The results indicate that the system under consideration is a feasible alternative for on site treatment and disposal of domestic sewage.     

锂离子电池有机电解液成膜添加剂的研究现状

文章综述了锂离子电池有机电解液成膜添加剂的作用原理，具体介绍了CO2、SO2、VC化合物、卤化物、有机铜盐以及马来酐等添加剂的研究现状。     

Inorganic–organic hybrid materials with zirconium oxoclusters as protective coatings on aluminium alloys

Inorganic–organic hybrid materials are attracting a strong scientific interest mainly for their outstanding inherent mechanical and thermal properties, which can be traced back to the intimate coupling of both inorganic and organic components. By carefully choosing the experimental parameters used for their synthesis, chemically and thermally stable acrylate-based hybrid material embedding the zirconium oxocluster Zr₄O₄(OMc)₁₂, where OMcCH₂C(CH₃)C(O)O, can be deposited as UV-cured films on aluminium alloys.

In particular, the molar ratios between the oxocluster and the monomer, the polymerisation time, the amount of photo-initiator and the deposition conditions, by using an home-made spray-coating equipment, were optimised in order to obtain the best performing layers in terms of transparency and hardness to coat aluminium alloy (AA1050, AA6060 and AA2024) sheets. Furthermore, it was also evaluated whether the hybrid coatings behave as barrier to corrosion.

Several coated samples were prepared and characterised. Environmental scanning electronic microscopy (ESEM) and scratch test were used to investigate the morphology of the films and to evaluate their scratch resistance, respectively. Electrochemical impedance spectroscopy (EIS) was performed in order to evaluate if the coatings actually protect the metallic substrate from corrosion.

In order to measure shear storage modulus (G′) and loss modulus (G″) of the materials used for coatings, bulk samples were also obtained by UV-curing of the precursors solution. Dynamical mechanical thermal analysis (DMTA) was performed in shear mode on cured disks of both the hybrid materials and pristine polymer for comparison. The values of T_g were read off as the temperatures of peak of loss modulus. The length and mass of all the samples were measured before and after the DMTA analysis, so that the shrinkage of the materials in that temperature range was exactly evaluated.     

用土壤含水层处理系统去除水库微污染有机物的试验研究

本文针对当前中国饮用水源污染以微污染为主的特点，以北京三家店水库原水和永定河河道砂为研究对象，设计了用于表征土壤含水层处理系统的一维土柱，进行污水净化效果的试验研究。结果表明，土壤含水层处理系统对三家店水库微污染水中的有机物有一定的去除效果，在0．12m／d的水力负荷条件下，对CODMo去除率虽然仅为15％，但是出水达到了地表水Ⅱ类水质标准；对BOD5的去除率达到了55％，可以被有效地去除。渗透速率相同时，水力负荷周期对去除效果的影响不明显，但在保证一定水力负荷的情况下，可适当延长落干期，恢复土壤的渗透能力，达到较好的处理效果。同时，土壤含水层处理系统的净化能力主要发生在土层50cm以内。     

有机羧酸钠盐对PET结晶和熔融行为的影响

采用差示扫描量热仪研究了5种具有不同取代基的苯甲酸钠盐作为结晶成核剂对聚对苯二甲酸乙二醇酯（HET）结晶和熔融行为的影响，并同滑石粉进行了对比。结果表明，成核剂的加入能明显改变PET的结晶和熔融行为。苯甲酸钠、对苯二甲酸甲酯单羧酸钠和对羟基苯甲酸钠提高既汀的熔融结晶温度（Tc）分别达22．93、21．7和19．37℃，但使PET降解严重；对苯酚钠甲酸钠能够提高Tc达17．75℃且对PET相对分子质量影响很小；对苯二甲酸二钠成核作用最差。低于滑石粉。此外，成核剂的成核能力越强，PET双熔融峰中的低温峰顶温度就越高。